Abstract

Groundwater aquifers make up the primary source of drinking water in Florida. It is imperative to protect and maintain water quality to ensure optimal drinking water conditions. Florida is known for being prone to sinkholes due to karst features. One sinkhole event occurred beneath a phosphogypsum stack, and leaked a large amount of radioactive waste in the Floridan aquifer, raising water quality concerns. To study the behavior of contaminant transport, the radioactive waste plume was modeled by coupling hydraulic and chemistry concepts. Adsorption was studied to see if it can serve as a potential remediation solution to the contaminant waste, using available adsorption knowledge and data from previous studies. Results suggest that simulating mineral adsorption helped limit how far the waste stack would travel in the aquifer, however it would still pose risk in water quality, as drinking water wells are situated along the path of the contaminant plume. Implementation of treatment wells and monitoring would ensure drinking water criteria are met. Acknowledging that the Floridan aquifer contains karst features that consist of limestone fractures and the rock matrix, groundwater flow patterns may be influenced over time. For instance, fractures (or conduits) can conduct larger amounts of groundwater at higher conductivities, which could have implications on groundwater/contaminant transport. To model this process, a karst evolution model utilizing hydraulic and chemistry concepts are applied in a basin in Florida. Results indicate the karst model reproduces head profiles and estimates the age of several conduits. A sensitivity analysis was conducted to investigate how karst evolution is influenced by hydraulic and chemistry parameters. Results show that fracture length has more influence on karst evolution, however other physical parameters show some influence as well. A karst conduit network was simulated for the Silver Springs springshed, based on obtained potentiometric head data. Implementing information on aquifer chemistry and fracture geometry resulted in a unique realization of a karst network. During this process, flow rates change direction, inducing backflow, which can have implications on groundwater resources. Overall, an improved understanding of karst processes can aid in better characterizing conduit flow patterns and improve water resources management.

Notes

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Graduation Date

2019

Semester

Summer

Advisor

Singh, Arvind

Degree

Doctor of Philosophy (Ph.D.)

College

College of Engineering and Computer Science

Department

Civil, Environmental, and Construction Engineering

Degree Program

Civil Engineering

Format

application/pdf

Identifier

CFE0007723

URL

http://purl.fcla.edu/fcla/etd/CFE0007723

Language

English

Release Date

August 2019

Length of Campus-only Access

None

Access Status

Doctoral Dissertation (Open Access)

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