ORCID

https://orcid.org/0009-0002-1452-6874

Keywords

MOF, dipoles, chirality, substitutional solid solutions

Abstract

In this work substitutional solid solutions of dipolar and chiral MOFs were made with predetermined structure, composition, and function. Through encoding the dipoles and chirality into the organic linkers and varying their incorporation into cubic porous interpenetrated zirconium MOF system the bulk dipolar and chiral properties were assessed. Specifically, the real and imaginary components of the polarization properties in respect to the dipoles and the optical properties in respects to chirality. It was found the bulk properties are dependent on the crystal structure and the inherent porosity of the MOFs themselves.

Completion Date

2025

Semester

Summer

Committee Chair

Andres Campiglia

Degree

Doctor of Philosophy (Ph.D.)

College

College of Sciences

Department

Chemistry

Format

PDF

Identifier

DP0029574

Language

English

Document Type

Thesis

Campus Location

Orlando (Main) Campus

Subjects

Metal-organic frameworks; Molecular crystals--Optical properties; Molecular crystals--Magnetic properties; Solid state chemistry--Research; Chirality--Industrial applications

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