Keywords

Laser Absorption Spectroscopy, Direct Absorption Spectroscopy, Wavelength Modulation Spectroscopy, Shock Tube, Detonation Facility

Abstract

Laser absorption spectroscopy (LAS) is a widely utilized diagnostic technique for probing gases in various combustion and detonation environments, including shock tubes, detonation tubes, and rotating detonation engines. Its advantages over other techniques, such as pyrometry or mass spectrometry, include its non-intrusiveness, noise rejection, high temporal and spatial resolution, and its ease of application across a wide range of temperatures, concentrations, and pressures. By relating the attenuation of light through a test environment to the properties of that environment, important combustion parameters such as speciation, temperature, pressure, and gas velocity can be extracted. These measurements are essential for optimizing rig performance, reducing emissions, improving safety, and validating combustion models and mechanisms. Within LAS, there exist multiple techniques, including direct absorption spectroscopy and wavelength modulation spectroscopy. Depending on the test environment, different considerations need to be made concerning the design of an LAS-based sensor. In this work, an in-depth analysis is provided regarding sensor design considerations, sensor construction and optimization, and sensor hardening. A LAS sensor composed of near-infrared and mid-infrared light sources, and capable of utilizing and rapidly switching between direct absorption and wavelength modulation techniques, is demonstrated and applied across multiple combustion and detonation environments. Emphasis is applied to constructing a modular sensor that can rapidly be interfaced with various reacting flow environments and can be utilized across a wide range of conditions. The sensor’s temperature, water and carbon oxide measurement capabilities are validated across shock tube and detonation tube facilities. Novel measurements are presented in Hydrogen-Oxygen and Methane-Oxygen detonation environments immediately following the arrival of the detonation wave and subsequent reflected waves. Additions are made to the existing literature concerning the development of modular sensors that can utilize multiple techniques with particular focus on expanding the literature on scanned-wavelength direct absorption spectroscopy at high pressure combustion environments.

Completion Date

2025

Semester

Fall

Committee Chair

Vasu Sumathi, Subith

Degree

Doctor of Philosophy (Ph.D.)

College

College of Engineering and Computer Science

Department

Mechanical and Aerospace Engineering

Format

PDF

Release Date

12-15-2026

Document Type

Dissertation

Campus Location

Orlando (Main) Campus

Subjects

Laser spectroscopy--Research; Laser spectroscopy--Industrial applications; Detonation waves--Measurement--Instruments; Combustion gases--Research; Infrared spectroscopy--Industrial applications

Available for download on Tuesday, December 15, 2026

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