A New Aromatic Organometallic Nonlinear-Optical Crystal - Bis-4-Nitropyridine-N-Oxide Cadmium Chloride

    Authors

    X. Dong; M. G. Liu; W. B. Hou; D. R. Yuan; M. H. Jiang; R. Quan;B. H. C. Chai

    Comments

    Authors: contact us about adding a copy of your work at STARS@ucf.edu

    Abbreviated Journal Title

    Mater. Res. Bull.

    Keywords

    CADMIUM; CHLORIDE; NITROPYRIDINE; ORGANOMETALLIC CRYSTAL; 2ND-HARMONIC GENERATION; Materials Science, Multidisciplinary

    Abstract

    A new nonlinear optical crystal BPONCC [Bis-4-nitropyridine-N- oxide cadmium chloride, Cd(NO2C5H4NO)(2)Cl-2], as a derivative of 4-nitropyridine-N-oxide,is reported for the first time. Preliminary results show that its powder intensity is about 8.2 times higher than that of urea, and the transparency cut-off wavelength is almost same as that of 3-methyl-4-nitropyridine-N-oxide (POM),which is about 420nm. Its melting point is much higher than that of the other 4-nitropyridine-N-oxide derivatives. The crystal structure belongs to space group Fdd2 with cell parameters a=11.644 Angstrom A, b=50.025 Angstrom A, c=3.808 Angstrom A.

    Journal Title

    Materials Research Bulletin

    Volume

    29

    Issue/Number

    1

    Publication Date

    1-1-1994

    Document Type

    Article

    Language

    English

    First Page

    73

    Last Page

    79

    WOS Identifier

    WOS:A1994ML03000009

    ISSN

    0025-5408

    Share

    COinS