Title

Accuracy of local exchange in the calculation of continuum wavefunctions

Authors

Authors

D. A. Biava; K. Bartschat; H. P. Saha;D. H. Madison

Comments

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Abbreviated Journal Title

J. Phys. B-At. Mol. Opt. Phys.

Keywords

ELECTRON-IMPACT IONIZATION; DIFFERENTIAL CROSS-SECTIONS; E, 2E; COLLISIONS; HARTREE-FOCK; POLARIZED ELECTRONS; LOW ENERGIES; SCATTERING; XENON; ARGON; ATOMS; Optics; Physics, Atomic, Molecular & Chemical

Abstract

It is well known that electron exchange can-play an important role in electron impact elastic, inelastic and ionization scattering from atoms and molecules. The proper theoretical treatment of exchange yields an inhomogeneous differential equation with a non-local exchange operator. To simplify the calculation, a local approximation is often made for this non-local operator. In this paper, we examine the accuracy of this approximation for the calculation of elastic scattering continuum waves in the presence of an argon ion with a single vacancy in the p-shell. It is found that one can. reliably use the local exchange approximation for ionization leading to s-state vacancies but not p state vacancies.

Journal Title

Journal of Physics B-Atomic Molecular and Optical Physics

Volume

35

Issue/Number

24

Publication Date

1-1-2002

Document Type

Article

Language

English

First Page

5121

Last Page

5130

WOS Identifier

WOS:000180629500017

ISSN

0953-4075

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