Title
Triatomic dissociative recombination theory: Jahn-Teller coupling among infinitely many Born-Oppenheimer surfaces
Abbreviated Journal Title
Faraday Discuss.
Keywords
QUANTUM-DEFECT THEORY; POTENTIAL-ENERGY SURFACE; VIBRATIONAL; PREIONIZATION; H-3(+); ACCURACY; SPECTRUM; HYDROGEN; D-3(+); SERIES; H-2; Chemistry, Physical
Abstract
The coupling of many Rydberg surfaces poses a stringent challenge for theoretical description. Yet simplifications arise because quantum defect ideas can be applied, which circumvents some of the usual difficulties that arise. We describe a theoretical technique capable of handling these complex interactions, which has already been applied with success to the dynamics of H-3 Rydberg states. The extensions necessary to treat the other isotopomers H2D+ and HD2+ are then discussed, along with a preliminary application.
Journal Title
Faraday Discussions
Volume
127
Publication Date
1-1-2004
Document Type
Article; Proceedings Paper
DOI Link
Language
English
First Page
413
Last Page
423
WOS Identifier
ISSN
1364-5498
Recommended Citation
"Triatomic dissociative recombination theory: Jahn-Teller coupling among infinitely many Born-Oppenheimer surfaces" (2004). Faculty Bibliography 2000s. 4499.
https://stars.library.ucf.edu/facultybib2000/4499
Comments
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