Authors

C. Drake; S. Deshpande;S. Seal

Comments

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"This article may be downloaded for personal use only. Any other use requires prior permission of the author and AIP Publishing. This article appeared in the linked citation and may be found originally at Applied Physics Letters."

Abbreviated Journal Title

Appl. Phys. Lett.

Keywords

GAS SENSORS; ABSORPTION; FILMS; O-2; Physics, Applied

Abstract

A correlation between the surface reactions and the electrical response of doped nano-metal-oxide-semiconductors exposed to reducing gas is established using Fourier transform infrared (FTIR) spectroscopy. The effect of processing temperature on the microstructure evolution and the electronic conduction of the nanocrystalline In-SnO2 is presented. Variation in the charge carrier density is correlated to the solid/gas reaction of In-SnO2 in the nanodomain using the Drude-Zener theory including Spitzer and Fan's [Phys. Rev. 99, 1893 (1955)] correction to accommodate for the quantum effects. Higher gas sensitivity for nanocrystalline size less than twice the space charge layer thickness is observed using in situ FTIR.

Journal Title

Applied Physics Letters

Volume

89

Issue/Number

14

Publication Date

1-1-2006

Document Type

Article

Language

English

First Page

3

WOS Identifier

WOS:000241056900106

ISSN

0003-6951

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