Co-assembly of Zn(SPh)(2) and organic linkers into helical and zig-zag polymer chains

    Authors

    Y. Liu; L. M. Yu; S. C. J. Loo; R. G. Blair;Q. C. Zhang

    Comments

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    Abbreviated Journal Title

    J. Solid State Chem.

    Keywords

    Coordination polymers; Single helicate; Zig-zag structure; Organic; linkers; COORDINATION POLYMERS; ASYMMETRIC CATALYSIS; ENANTIOSELECTIVE; SEPARATION; CHALCOGENIDE CLUSTERS; HOMOCHIRAL FRAMEWORKS; CHIRAL; RECOGNITION; LIGANDS; TEMPLATE; EXCHANGE; CONSTRUCTION; Chemistry, Inorganic & Nuclear; Chemistry, Physical

    Abstract

    Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)(2)(TPYTA)(EG)](n) (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)(2)(BPyVB)](n) (2), were synthesized under solvothermal conditions at 150 degrees C or room temperature by the co-assembly of Zn(SPh)(2) and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl)benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2(1)/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 degrees C and 210 degrees C. (C) 2012 Elsevier Inc. All rights reserved.

    Journal Title

    Journal of Solid State Chemistry

    Volume

    191

    Publication Date

    1-1-2012

    Document Type

    Article

    Language

    English

    First Page

    283

    Last Page

    286

    WOS Identifier

    WOS:000305670700042

    ISSN

    0022-4596

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