Two-Photon Absorption Circular-Linear Dichroism on Axial Enantiomers

Authors

    Authors

    C. Toro; L. De Boni; N. Lin; F. Santoro; A. Rizzo;F. E. Hernandez

    Comments

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    Abbreviated Journal Title

    Chirality

    Keywords

    two-photon absorption; dichroism; circularly polarized light; bi(naphthols); non linear chiral spectroscopy; CHIRAL MOLECULES; ENANTIOSELECTIVE CATALYSIS; NONLINEAR OPTICS; SPECTROSCOPY; PROTEINS; 1, 1'-BINAPHTHYLS; POLYPEPTIDES; DISCOVERY; DENSITY; Chemistry, Medicinal; Chemistry, Analytical; Chemistry, Organic; Pharmacology & Pharmacy

    Abstract

    We report on the experimental-theoretical analysis of degenerated two-photon absorption circular-linear dichroism (2PA-CLD) in (S)-(2)-1,10-bi(2-naphthol) and (R)-(1)-1,10-bi(2-naphthol) dissolved in THF. 2PA-CLD reveals similarities and differences between optical polarization states for the different enantiomers. These results unveil the potential applications of 2PA-CLD for the study and identification of chiral molecules with active and pivotal role in biological systems and the systematic design of chiral photonic structures. Chirality 22:E202-E210, 2010. (C) 2010 Wiley-Liss, Inc.

    Journal Title

    Chirality

    Volume

    22

    Issue/Number

    1E

    Publication Date

    1-1-2010

    Document Type

    Article

    Language

    English

    First Page

    E202

    Last Page

    E210

    WOS Identifier

    WOS:000283779400026

    ISSN

    0899-0042

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