Keywords

Herbicides, Polystyrene-supported cobalt(II) diiminato complexes, Trisite and disite quaternary phosphonium salts, Polymer-supported oxidation catalysis, Nucleophilic substitution reactions (phase-transfer catalyzed), Synthesis of potential herbicide analogues

Abstract

This report consists of three parts. Part I involved the synthesis and evaluation of some polymer supported homogeneous oxidation catalysts – specifically, the synthesis of polystyrene 2(bis-salicylaldehyde) 2-methyl propylene-1, 3-diiminato cobalt (II) and polystyrene 2(bis-2, 4-pentanedione) 2-methyl propylene-1, 3-diiminato cobalt (II). Part II involved the synthesis of both soluble and insoluble phase transfer catalysts designed to catalyze nucleophilic substitution reactions. Trisite quaternary phosphonium and disite quaternary phosphonium salts were prepared. Part III involved the synthesis of several potential herbicides.

Notes

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Graduation Date

1984

Semester

Fall

Advisor

Idoux, John P.

Degree

Master of Science (M.S.)

College

College of Arts and Sciences

Degree Program

Industrial Chemistry

Format

PDF

Pages

58 pages

Language

English

Rights

Public Domain

Length of Campus-only Access

None

Access Status

Masters Thesis (Open Access)

Identifier

DP0015942

Subjects

Organometallic polymers--Synthesis; Phase-transfer catalysts; Catalysts--Research; Polymers--Synthesis; Herbicides--Synthesis

Contributor (Linked data)

John P. Idoux (Q58972436)

Accessibility Status

Searchable text

Included in

Chemistry Commons

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