Abstract

This report discusses research involving the preparation of germinal difluorodienes. Free radical addition of dibromodifluoromethane to 1-hexene and cyclohexene was performed, followed by a double dehydrohalogenation to yield 1,1-difluoro-1,3-heptadiene and 3-(difluoromethylene)cyclohexene, respectively. NMR, IR, and mass spectral data were obtained and presented as groundwork for further research. A study comparing the free radical initiators, benzoyl peroxide and 2,2’-azobis-(2-methyl)proprionitrile (AIBN) was included, showing neither as ideal initiators for the free radical additions performed. The relative stabilities of the bromodifluoromethyl and the difluoroiodomethyl radicals were approximated. A Diels-Alder reaction of 1,1-difluoro-1,3-heptadiene with 4-phenyl-1,2,4-triazoline-3,5-dione produced the expected [4 + 2] cycloadduct in good yield.

Notes

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Graduation Date

1987

Semester

Fall

Advisor

Elsheimer, Seth Robert

Degree

Master of Science (M.S.)

College

College of Arts and Sciences

Department

Chemistry

Degree Program

Industrial Chemistry

Format

PDF

Pages

45 p.

Language

English

Rights

Public Domain

Length of Campus-only Access

None

Access Status

Masters Thesis (Open Access)

Identifier

DP0020552

Contributor (Linked data)

Elsheimer, Seth Robert [VIAF]

Elsheimer, Seth Robert [LC]

Accessibility Status

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