Reactions of (3-(DIMETHYLAMINO)-2-AZAPROP-2-EN-1-YLIDENE) Dimethylammonium Chloride (Gold's Reagent) with Carboxylic Acid Derivatives and Grignard Reagents

Author

Dale E. Polk, University of Central Florida

Keywords

Chemical tests and reagents, Chemistry -- Organic

Abstract

An azavinamidium salt, [3-(Dimethylamino)-2-azaprop-2-en-l-ylidene] dimethylammonium chloride was reacted with primary amides, esters containing an ╬▒-methylene group and Grignard reagents. The reaction of this azavinamidium salt with amides and esters produced respectively, acyl amidines and enamino esters. Both of these products were produced in high yields by using relatively mild conditions. Reaction of the salt with Grignard reagents resulted in a novel synthesis of aldehydes. This aldehyde synthesis was shown to be of general utility and to proceed in high yields.

Notes

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Graduation Date

Summer 1981

Degree

Master of Science (M.S.)

College

College of Arts and Sciences

Degree Program

Industrial Chemistry

Format

PDF

Pages

34 p.

Language

English

Rights

Public Domain

Length of Campus-only Access

None

Access Status

Masters Thesis (Open Access)

Identifier

DP0013450

STARS Citation

Polk, Dale E., "Reactions of (3-(DIMETHYLAMINO)-2-AZAPROP-2-EN-1-YLIDENE) Dimethylammonium Chloride (Gold's Reagent) with Carboxylic Acid Derivatives and Grignard Reagents" (1981). Retrospective Theses and Dissertations. 581.
https://stars.library.ucf.edu/rtd/581

Accessibility Status

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