Title

Electronic Quenching Of The A1Σ+ State Of Nah

Abstract

We have measured the rates for quenching of the v = 4 and v = 5 vibrational levels of the A1Σ+ state of sodium hydride using helium, argon, and nitrogen as the quenching gas. The measured rates are compared with earlier results for state-to-state quenching rates. The measured rates for quenching by helium and argon are similar, whereas that for quenching by nitrogen is an order of magnitude higher. In addition, at high nitrogen gas pressures the fluorescence was observed to undergo large scale intensity fluctuations. It is suggested that this may be due to a chemical rather than a physical mechanism. © 1995.

Publication Date

11-3-1995

Publication Title

Chemical Physics Letters

Volume

245

Issue

4-5

Number of Pages

427-431

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1016/0009-2614(95)01022-2

Socpus ID

58149323396 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/58149323396

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