Title

A New Aromatic Organometallic Nonlinear Optical Crystal: [Bis-4-Nitropyridine-N-Oxide Cadmium Chloride]

Abstract

A new nonlinear optical crystal BPONCC [Bis-4-nitropyridine-N- oxide cadmium chloride, Cd(NO2C5H4NO)2Cl2], as a derivative of 4-nitropyridine-N-oxide, is reported for the first time. Preliminary results show that its powder intensity is about 8.2 times higher than that of urea, and the transparency cut-off wavelength is almost same as that of 3-methyl-4-nitropyridine-N-oxide (POM), which is about 420nm. Its melting point is much higher than that of the other 4-nitropyridine-N-oxide derivatives. The crystal structure belongs to space group Fdd2 with cell parameters a = 11.644 A ̊, b = 50.025 A ̊, c = 3.808 A ̊. © 1993.

Publication Date

1-1-1994

Publication Title

Materials Research Bulletin

Volume

29

Issue

1

Number of Pages

73-79

Document Type

Article

Identifier

scopus

Personal Identifier

scopus

DOI Link

https://doi.org/10.1016/0025-5408(94)90107-4

Socpus ID

0028315789 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/0028315789

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