Title
A Surface Coordination Network Based On Substrate-Derived Metal Adatoms With Local Charge Excess
Keywords
Coordination modes; Density functional calculations; Scanning probe microscopy; Structure elucidation; Surface chemistry
Abstract
Surface safari: 9,10-Anthracenedicarbonitrile (DCA) molecules adsorbed on a Cu(111) surface can be titrated by gradual annealing of the substrate to form trigonal planar Cu(DCA)3 complexes and, ultimately, a hexagonal network (see picture) with a Cu2(DCA)3 stoichiometry. As a result of charge donation from the substrate, the coordinated Cu adatom remains electrically neutral despite donating approximately 1/3 charge to each Cu-N bond. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
Publication Date
10-20-2008
Publication Title
Angewandte Chemie - International Edition
Volume
47
Issue
44
Number of Pages
8442-8445
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1002/anie.200802543
Copyright Status
Unknown
Socpus ID
54249138097 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/54249138097
STARS Citation
Pawin, Greg; Wong, Kin L.; Kim, Daeho; Sun, Dezheng; and Bartels, Ludwig, "A Surface Coordination Network Based On Substrate-Derived Metal Adatoms With Local Charge Excess" (2008). Scopus Export 2000s. 9234.
https://stars.library.ucf.edu/scopus2000/9234