Title
Mechanochemical Routes For The Synthesis Of Acetyl- A Nd Bis-(Imino)Pyridine Ligands And Organometallics
Abstract
Organometallic precatalysts play a pivotal role in organic synthesis. However, their preparation often relies on multiple time, energy, and solvent intensive steps, including the synthesis of supporting organic ligand structures, and finally installation on the desired metal centres. We report the sustainable mechanochemical synthesis of acetyl- A nd bis-(imino)pyridine pincer complexes, a ubiquitous ligand class for organometallic precatalysts. The approach is extended to the one-pot synthesis of acetyl(imino)pyridine-CoCl2, where the ligand is formed in situ.
Publication Date
1-1-2018
Publication Title
Dalton Transactions
Volume
47
Issue
47
Number of Pages
16876-16884
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1039/c8dt03608j
Copyright Status
Unknown
Socpus ID
85058176129 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/85058176129
STARS Citation
Shaw, Thomas E.; Shultz, Lorianne R.; Garayeva, Louiza R.; Blair, Richard G.; and Noll, Bruce C., "Mechanochemical Routes For The Synthesis Of Acetyl- A Nd Bis-(Imino)Pyridine Ligands And Organometallics" (2018). Scopus Export 2015-2019. 8805.
https://stars.library.ucf.edu/scopus2015/8805