Mechanochemical Routes For The Synthesis Of Acetyl- A Nd Bis-(Imino)Pyridine Ligands And Organometallics

Abstract

Organometallic precatalysts play a pivotal role in organic synthesis. However, their preparation often relies on multiple time, energy, and solvent intensive steps, including the synthesis of supporting organic ligand structures, and finally installation on the desired metal centres. We report the sustainable mechanochemical synthesis of acetyl- A nd bis-(imino)pyridine pincer complexes, a ubiquitous ligand class for organometallic precatalysts. The approach is extended to the one-pot synthesis of acetyl(imino)pyridine-CoCl2, where the ligand is formed in situ.

Publication Date

1-1-2018

Publication Title

Dalton Transactions

Volume

47

Issue

47

Number of Pages

16876-16884

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1039/c8dt03608j

Socpus ID

85058176129 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/85058176129

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