Anodically Coupled Electrolysis For The Heterodifunctionalization Of Alkenes

Abstract

The emergence of new catalytic strategies that cleverly adopt concepts and techniques frequently used in areas such as photochemistry and electrochemistry has yielded a myriad of new organic reactions that would be challenging to achieve using orthodox methods. Herein, we discuss the strategic use of anodically coupled electrolysis, an electrochemical process that combines two parallel oxidative events, as a complementary approach to existing methods for redox organic transformations. Specifically, we demonstrate anodically coupled electrolysis in the regio- and chemoselective chlorotrifluoromethylation of alkenes.

Publication Date

2-21-2018

Publication Title

Journal of the American Chemical Society

Volume

140

Issue

7

Number of Pages

2438-2441

Document Type

Article

Personal Identifier

scopus

DOI Link

https://doi.org/10.1021/jacs.7b13387

Socpus ID

85042355844 (Scopus)

Source API URL

https://api.elsevier.com/content/abstract/scopus_id/85042355844

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