Title
One-Pot Tandem Photoredox And Cross-Coupling Catalysis With A Single Palladium Carbodicarbene Complex
Keywords
carbenes; cross-coupling; palladium; photocatalysis; reaction mechanisms
Abstract
The combination of conventional transition-metal-catalyzed coupling (2 e− process) and photoredox catalysis (1 e− process) has emerged as a powerful approach to catalyze difficult cross-coupling reactions under mild reaction conditions. Reported is a palladium carbodicarbene (CDC) complex that mediates both a Suzuki–Miyaura coupling and photoredox catalysis for C−N bond formation upon visible-light irradiation. These two catalytic pathways can be combined to promote both conventional transition-metal-catalyzed coupling and photoredox catalysis to mediate C−H arylation under ambient conditions with a single catalyst in an efficient one-pot process.
Publication Date
4-16-2018
Publication Title
Angewandte Chemie - International Edition
Volume
57
Issue
17
Number of Pages
4622-4626
Document Type
Article
Personal Identifier
scopus
DOI Link
https://doi.org/10.1002/anie.201800951
Copyright Status
Unknown
Socpus ID
85043489328 (Scopus)
Source API URL
https://api.elsevier.com/content/abstract/scopus_id/85043489328
STARS Citation
Hsu, Yu Cheng; Wang, Vincent C.C.; Au-Yeung, Ka Chun; Tsai, Chung Yu; and Chang, Chun Chi, "One-Pot Tandem Photoredox And Cross-Coupling Catalysis With A Single Palladium Carbodicarbene Complex" (2018). Scopus Export 2015-2019. 9800.
https://stars.library.ucf.edu/scopus2015/9800