Keywords
Knight shift, superconductivity
Abstract
This dissertation is the beginning of the development of a microscopic theory of the Knight shift. The Knight shift experiment has been used in superconductivity research throughout history, however, a complete understanding of the Knight shift in conventional as well as unconventional superconductors does not yet exist. Motivated by the results of a literature review, which discusses Knight shift anomalies in multiple superconducting materials, this research studies a new model of the Knight shift, which involves the processes involved in nuclear magnetic resonance measurements in metals. The result of this study is a microscopic model of nuclear magnetic resonance in metals. The spins of the spin-1/2 local nucleus and its surrounding orbital electrons interact with the arbitrary constant ${\bf B}_0$ and perpendicular time-oscillatory magnetic inductions ${\bf B}_1(t)$ and with each other via an anisotropic hyperfine interaction. An Anderson-like Hamiltonian describes the excitations of the relevant occupied local orbital electrons into the conduction bands, each described by an anisotropic effective mass with corresponding Landau orbits and an anisotropic spin ${\bf g}$ tensor. Local orbital electron correlation effects are included using the mean-field decoupling procedure of Lacroix. The metallic contributions to the Knight shift resonance frequency and linewidth shifts are evaluated to leading orders in the hyperfine and Anderson excitation interactions. While respectively proportional to $(B_1/B_0)^2$ and a constant for weak $B_0 > > B_1$, both shifts are shown to depend strongly upon ${\bf B}_0$ when a Landau level is near the Fermi energy.
Notes
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Graduation Date
2015
Semester
Fall
Advisor
Klemm, Richard
Degree
Doctor of Philosophy (Ph.D.)
College
College of Sciences
Department
Physics
Degree Program
Physics
Format
application/pdf
Identifier
CFE0005954
URL
http://purl.fcla.edu/fcla/etd/CFE0005954
Language
English
Release Date
December 2015
Length of Campus-only Access
None
Access Status
Doctoral Dissertation (Open Access)
Subjects
Dissertations, Academic -- Sciences; Sciences -- Dissertations, Academic
STARS Citation
Hall, Bianca, "Microscopic Theory of the Knight Shift" (2015). Electronic Theses and Dissertations. 1372.
https://stars.library.ucf.edu/etd/1372