Keywords
Terphenyl liquid crystals, Phenyl-Tolane liquid crystals, high birefringence
Abstract
High birefringence (Δn > 0.4) nematic liquid crystals are particularly attractive for infrared applications because they enable a thinner cell gap to be used for achieving fast response time and improved diffraction efficiency. In this thesis, the mesomorphic and electro‐optic properties of several new fluorinated isothiocyanate (NCS) terphenyl and phenyl tolane single compounds and mixtures are reported. The single compounds demonstrated Δn~0.35‐0.52 in the visible spectral region at room temperature and exhibit relatively low viscosity. It was found that lateral fluorine substitutions and short alkyl chains eliminate smectic phase and lower the melting temperature of the single compounds. However, the consequence of using highly conjugated compounds to improve electro‐optic properties is that the nematic phase is exhibited at high temperatures, over 100°C, and therefore single compounds cannot be used for device applications. Therefore, several mixtures based on the terphenyl and phenyl‐tolane compounds were formulated and evaluated. The purpose of mixtures is to find the optimum balance between electro‐optic performance and the mesomorphic properties that determine the operating temperature range. It was found that mixture formulations greatly improved mesomorphic properties to produce nematic phase at or near room temperature and suppressed smectic phase to below 0°C or eliminating completely. The analysis presented evaluates the benefits of lowering the operating temperature versus the consequence of degrading the electro‐optic properties.
Notes
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Graduation Date
2007
Semester
Fall
Advisor
Wu, Shin-Tson
Degree
Master of Science (M.S.)
College
College of Optics and Photonics
Department
Optics and Photonics
Degree Program
Optics
Format
application/pdf
Identifier
CFE0001882
URL
http://purl.fcla.edu/fcla/etd/CFE0001882
Language
English
Release Date
December 2007
Length of Campus-only Access
None
Access Status
Masters Thesis (Open Access)
STARS Citation
Parish, Amanda Jane, "High Birefringence Liquid Crystals For Optical Communications" (2007). Electronic Theses and Dissertations. 3290.
https://stars.library.ucf.edu/etd/3290