Keywords
Thermoresponsive, PNIPAAm, Nanostructure, Layer-by-Layer, Logistic function, Microfluidic flow regulation, Pressure differential
Abstract
This work describes the modeling, synthesis, integration and characterization of a novel nanostructure embedded thermoresponsive material for microfluidic applications. The innumerable applications of thermoresponsive surfaces in the recent years have necessitated the development of a rigorous mathematical treatment for these surfaces to understand and improve their behavior. An analytical model is proposed to describe the transfer characteristic (variation of contact angle versus temperature) of a unique switchable, nanostructured, thermoresponsive surface consisting of silica nanoparticles and the thermoresponsive polymer, Poly(N-isopropylacrylamide ) (PNIPAAm) which changes its wetting angle upon heating. Important metrics such as the absolute lower critical solution temperature, threshold & saturation temperatures and gain are modeled and quantified by mathematical expressions. Based on the modeling, a heat source for the thermoresponsive surface was integrated on the glass substrate itself to create a fully functional smart surface. The design and fabrication of a smart platform consisting of the switchable, nanostructured, thermoresponsive surface with an integrated gold microheater for wettability control and its time response analysis was conducted. The insight gained into the behavior of the thermoresponsive surface by using the analytical model, aided the effort in the effective integration of the surface into a microfluidic channel for flow regulation applications. The implementations of novel microfluidic flow regulator concepts were tested. The aim is to integrate a regulator function to a channel surface utilizing the layer-by-layer (LBL) deposition technique. The characterization and pressure differential study of the microfluidic regulators was carried out on simple straight microchannels which were selectively coated with the thermoresponsive surface. Theoretical and experimental studies were performed to determine the important characteristic parameters including capillary, Weber and Reynolds numbers. The pressure differential data was used to develop critical operating specifications. This work lays out a new microfluidic device concept consisting of a channel with a built-in regulatory function.
Notes
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Graduation Date
2008
Advisor
Cho, Hyoung Jin
Degree
Doctor of Philosophy (Ph.D.)
College
College of Engineering and Computer Science
Department
Electrical Engineering and Computer Science
Degree Program
Electrical Engineering
Format
application/pdf
Identifier
CFE0002368
URL
http://purl.fcla.edu/fcla/etd/CFE0002368
Language
English
Release Date
September 2009
Length of Campus-only Access
None
Access Status
Doctoral Dissertation (Open Access)
STARS Citation
Londe, Ghanashyam, "Integration Of A Nanostructure Embedded Thermoresponsive Polymer For Microfluidic Applications" (2008). Electronic Theses and Dissertations. 3598.
https://stars.library.ucf.edu/etd/3598