Title

Susceptibility Discontinuity In Single-Crystal C60

Authors

Authors

W. L. Luo; H. Wang; R. S. Ruoff; J. Cioslowski;S. Phelps

Comments

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Abbreviated Journal Title

Phys. Rev. Lett.

Keywords

Orientational-Ordering Transition; Current Magnetic-Susceptibility; Icosahedral C-60; Spectroscopy; Buckminsterfullerene; Physics, Multidisciplinary

Abstract

Magnetization of a large single C60 crystal was measured as functions of applied field and temperature. At T = 260 K, a discontinuity in susceptibility was observed. The relative change in total moment is 1.2%, independent of applied field to within experimental accuracy. This discontinuity is attributed to the change in the intramolecular geometry at the orientational order-disorder transition. This is the first experimental demonstration that the cooperative phase transition affects the magnetic susceptibility of a single molecule.

Journal Title

Physical Review Letters

Volume

73

Issue/Number

1

Publication Date

1-1-1994

Document Type

Article

Language

English

First Page

186

Last Page

188

WOS Identifier

WOS:A1994NV63100047

ISSN

0031-9007

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