Title

Insight into reactions and interface between boron nitride nanotube and aluminum

Authors

Authors

D. Lahiri; V. Singh; L. H. Li; T. Xing; S. Seal; Y. Chen;A. Agarwal

Comments

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Abbreviated Journal Title

J. Mater. Res.

Keywords

MECHANICAL-PROPERTIES; CARBON NANOTUBES; MATRIX COMPOSITES; ELASTIC-MODULUS; GROWTH; FILMS; MICROSTRUCTURE; FABRICATION; BEHAVIOR; Materials Science, Multidisciplinary

Abstract

Nature and mechanism of interfacial reactions between boron nitride nanotubes (BNNTs) and aluminum matrix at high temperature (650 degrees C) are studied using high-resolution transmission electron microscopy (HRTEM). This study analyzes the feasibility of the use of BNNTs as reinforcement in aluminum matrix composites for structural application, for which interface plays a critical role. Thermodynamic comparison of aluminum (Al)-BNNT with analogous Al-carbon nanotube (Al-CNT) system reveals lesser amount of reaction in the former. Experimental observation also reveals thin (similar to 7 nm) reaction-product formation at Al-BNNT interface even after 120 min of exposure at 650 degrees C. The spatial distribution of the reaction-product species at the interface is governed by the competitive diffusion of N, Al, and B. Morphology of the reaction products are influenced by their orientation relationship with BNNT walls. A theoretical prediction on Al-BNNT interface in macroscale composite suggests the formation of strong bond between the matrix and reinforcement phase.

Journal Title

Journal of Materials Research

Volume

27

Issue/Number

21

Publication Date

1-1-2012

Document Type

Article

Language

English

First Page

2760

Last Page

2770

WOS Identifier

WOS:000310706100008

ISSN

0884-2914

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