Keywords
Agricultural chemistry, Chemistry, Organic
Abstract
This report discusses research in three areas of organic synthesis: The synthesis of potential insecticides; the reinvestigation of the reaction of hexamethylphosphoramide with ketoximes; and the regioselective fluoroalkoxylation and polyfluoroalkoxylation of activated dihalobenzenes and dihaloheterocycles. In Part I, a series of N-(4-heteroaryloxybenzoyl)-N'-(2, 3-dichlorobenzoyl) hydrazines are synthesized, and attempts at cyclic dehydration to the corresponding 2, 5-disubstituted-1, 3, 4-oxadiazoles are discussed. In Part II, the synthesis of N, N-dimethyl-N'-aryl amidines by the reaction of aryl alkyl and diaryl ketoximes with HMPA is discussed. In Part III, a series of activated dihalobenzenes and dihaloheterocycles are reacted with sodium trifluoroethoxide to study the possibility of regioselective fluoroalkoxylation and polyfluoroalkoxylation of these activated substances.
Notes
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Graduation Date
1984
Semester
Spring
Advisor
Gupton, John T.
Degree
Master of Science (M.S.)
College
College of Arts and Sciences
Degree Program
Industrial Chemistry
Format
Pages
39 p.
Language
English
Rights
Public Domain
Length of Campus-only Access
None
Access Status
Masters Thesis (Open Access)
Identifier
DP0015873
STARS Citation
DeCrescenzo, Gary A., "A Three Part Research Report: The Synthesis of Potential Insecticides, N-(4-Heteroaryloxybenzoyl)-N'-(2,4-Dichlorobenzoyl) Hydrazines: A Reinvestigation of Hexamethylphosphoramide with Ketoximes; Regioselective Fluoralkoxylation and Polyfluoroalkoxylation of Activated Dihalobenzenes and Dihaloheterocycles" (1984). Retrospective Theses and Dissertations. 4692.
https://stars.library.ucf.edu/rtd/4692
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Accessibility Status
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